[ Post New Message | Post Reply to this One | Send Private Email to Ted Kaufman | Help ]

Response to Pyrocat HD in tubes?

from Ted Kaufman (writercrmp@aol.com)
Catechol or pyrocatechin developers (example: Pyrocat-HD) oxidize much like pyrogallol developers (example: PMK). When processed in trays or tanks with intermittent agitation, the oxidation occurs at a relatively controlled rate, which contributes both to the stain and the lovely tonality. With continuous agitation (rotary), both type developers oxidize too rapidly and underdevelopment will result.

I know of two ways to deal with this. One, and by far the simplest, is to increase the amount of developing agent (typically part "A"). I would try somewhere between 50-100% increase. With the activating agents used in most catechol or pyrogallol--sodium metaborate in PMK and sodium or potassium carbonate in catechol types--it will probably not be necessary to increase the activator.

The other alternative is to an additive to reduce the oxidation. I'm having a brain lapse at the moment and can't think of the chemical's name, but the trade name is Calgon. Also, I'd have to check my notes- -which are not with me at the moment--to tell you the amount to add, but if someone else cannot provide this, email me and I'll give you a starting point. I believe Gordon Hutchings mentions it in his Pyro book.

As I recall, the rollo pyro formula uses *both* these fixes.

Ahhh, it's call EDTA (Calgon)!

(posted 8288 days ago)

[ Previous | Next ]