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Response to does d76 get more grainy with age?

from John Hicks (jbh@magicnet.net)
> Kodak D-76 is notorious for gaining activity

I wonder how valid that is for packaged D-76; it contains a buffer to prevent that problem, and is said to be actually D-76d, which is consistent with the info in the MSDS.

As for increased graininess, higher development temperatures yield increased graininess (Henry, _Control in Black and White Photography_) with the "best" temperature being 68F-72F.

While I doubt developer age is the problem, four months is a fairly long time to have a jug of D-76 kicking around. I'd suggest simply mixing smaller quantities. If the reason for mixing a gallon is cost of the quart size, you might consider mixing your own developers. A relatively inexpensive balance scale makes it easy; otherwise conversion tables to use tablespoon'n'teaspoon methods can be found.

The simplest is D-23.

D-23:

Water 750ml 125F

Metol 7.5g

Sodium sulfite 100g

Water to make 1.0L

Use straight or diluted up to 1:3. Developing times will be longer than D-76 but neg characteristics will be pretty much the same. Contrary to common opinion, D-23 isn't a "soft-working" developer; it can yield the same curve shape and CI as D-76 if the development time is long enough. I believe most who consider D-23 to be a low contrast developer simply aren't developing long enough.

A D-76 variant, D-76H, is easy to make. It works the same as D-76 but hydroquinone is eliminated to avoid any concerns about the pH increase with age activating hydroquinone.

D-76H

Water 750ml 125F

Metol 2.5g

Sodium sulfite 100g

Borax (20 Mule Team) 2g

Water to make 1.0L

(posted 8512 days ago)

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